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A Comparison of Oxidation Processes

Organic contaminants are oxidized under vigorous conditions employing various combinations of light, heat, pressure, catalysis, and chemicals. The organics are oxidized predominately to carbon dioxide and water. Oxidation technologies are effective and some no longer have high capital and operating costs.

 

Photochemical Oxidation: Ultraviolet light (UV) in combination with hydrogen peroxide, ozone, or inorganic catalysts results in generation of free radical oxidants that can degrade various organic chemicals. This process can be effective; however, energy and capital costs can be high and has problems with turbidity.

 

 

Chemical Oxidation: Chemical oxidation is similar to photochemical oxidation but uses chemical reagents solely to generate free radicals. For example, Fenton's reagent utilizes ferrous iron and hydrogen peroxide to generate free radicals. This process is relatively inexpensive but can generate a large quantity of sludge.

 

 

 

Supercritical Oxidation: This process uses high temperatures and pressures above the critical point of water to yield a highly oxidative environment that can destroy organic chemicals. These chemicals are oxidized to carbon dioxide and water. The process is very efficient and NO LONGER has high energy and capital costs due to using high power low cost semiconductors to create switch.

 

Figure 1  supercritical water oxidation Pulsed Plasma process

 

 

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